Polyether Block Amides
Polyether Block Amides
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Mechanical Properties




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1. A large range of mechanical properties

2. Elastic properties

3. Elastic return

4. Fatigue resistance

5. Outstanding properties at low temperature

6. Dynamic Mechanical Analysis (DMA)

 

 

1. A large range of mechanical properties

1.1 Range of hardness

Hardness can be defined as the resistance of a material to an indentation deformation. The higher the hardness, the better the material’s resistance to the indenting deformation will be. For thermoplastic materials, the hardness is characterized with the Shore D reference, whereas the Shore A reference is used for elastomers and low modulus materials.

 

Shore D Hardness:

 

This test enables the determination of the penetration depth in the sample under a given load and during a fixed time lap. The indentation device is not supposed to be deformable.
The instant hardness (the measurement does not last longer than one second) or the hardness after 15 seconds is typically used for pebax®.
The standard used for this measurement is ISO 868, which is equivalent to ASTM standard D2240.

 

Pebax® Grade

Shore A

Hardness

 

Shore D

Hardness

 
  Instantaneous After 15 s Instantaneous After 15 s
         
2533 SN01 77 74 27 22
3533 SN01 82 80 33 25 
4033 90 89 41 34 
MX 1205 92 90  46  41 
5533 - - 54  50
6333 - - 64 58
7033 - - 69 61
7233 - - 69 61

 

1.2 Range of flexural modulus

The flexural resistance can be measured thanks to the three point method: a sample is positioned on two supports. A force is applied in the middle, leading to the so-called three point loading (see figure). This test combines compression, tensile and shear solicitations in the material. Two essential material characteristics are measured thanks to this test: the flexural elasticity modulus and the flexural stress at break.

 

 

The flexural stress versus strain curve is then plotted to determine the flexural modulus.

 

 

 

 

 

The flexural modulus corresponds to the tangent of the stress versus strain curve measured in the initial linear portion where the material is only slightly deformed.


 

The flexural modulus value is expressed in MPa. These tests are generally performed using the ISO 178 standard or the ASTM D 790 standard. When using the ISO 178 standard, the sample geometries are 80 x 10 x 4 mm3 bars.

 

Pebax® Grade ASTM D 790
After Conditioning
ISO 178**
After Conditioning
  Flexural Modulus (MPa) Flexural Modulus (MPa)
2533 14 12 
3533 20  21 
4033 81  77 
MX 1205 93  86 
5533 164  170 
6333 278  285 
7033 379  390 
7233 518  513 

 

This graph illustrates the flexural modulus range offered by the pebax® 33 series, going from approximately 10 to 500 MPa.

 

 

 

 

 1.3 High tensile strength

The tensile stress-strain curves shown in the graphs below have been obtained using ASTM D638, after a standard conditioning of 14 days at 23°C and under 50% relative humidity.

 

 

 

 

 

Tensile tests give access to:

  • Tensile modulus
  • Stress and strain at break
  • Stress at a given deformation
  • Stress and strain at yield

The stress and strain at break values can be obtained from tensile tests at 23°C using two possible standards: the ISO 527 1 BA standard (using a strain rate of 200 mm/min and ISO 527-1BA type samples) or the ASTM D 638 standard (using a strain rate of 500 mm/min and ASTM D638 type IV samples).

 

 

Pebax®Grade Strain (%) Stress (MPa) Strain (%) Stress (MPa)
V=200 mm / min V=500 mm / min
ISO 527 1 BA ASTM D 638 type IV
2533 751 28 826 21
3533 615 26 692 27
4033 408 26 466 30
MX1205 623 37 655 38
5533 468 44 514 48
6333 416 49 438 43
7033 392 52 402 44
7233 319 54 357 45

 

It is often useful to determine the stress and strain values of pebax® for a given elongation, as the modulus and strain at break values are not always a reflection of the solicitation of the material in a given application.

 

 

Tensile Stress for an

elongation of

2533 3533 4033 MX1205 5533  6333 7033 7233
ISO 527 1 BA
V=500 mm/min
10 % 1.01 1.47 5.67 5.28 9.16 12.85 19.52 25.14
50 % 3.03 4.11 8.97 8.32 11.67 14.77 19.39 22.33
100 % 3.89 5.05 10.17 8.50 12.28 15.37 19.72 22.96
300 % 6.38 9.01 18.32 12.76 21.65 30.19 36.93 43.40
ASTM D 638
TYPE IV
V= 500
mm/min
10 % 1.06 1.61 5.14 5.53 10 14.22 21.62 28.65
50 % 3.21 4.55 8.87 9.12 13.21 16.55 21.77 25.01
100 % 4.16 5.78 10.50 9.14 13.63 16.92 21.05 24.82
300 % 6.40 9.47 19.30 12.23 20.90 27.47 31.55 38.05